导电聚吡咯薄膜的大过电位现象
黄赣辉; 邓少平; 詹月华
南昌大学食品科学教育部重点实验室; 浙江工商大学感官科学实验室; 浙江工商大学感官科学实验室 江西南昌330047; 浙江杭州310035;
HUANG Gan-hui~(1,2),DENG Shao-ping~(2*),ZHAN Yue-hua~2(1.The Key Laboratory of Food Science of MOE,Nanchang University,Nanchang 330047,China;2.Sensory Science Laboratory,Zhejiang Gongshang University,Hangzhou 310035,China)
摘要 导电聚吡咯薄膜的大过电位是一个有趣而被忽视的现象,针对它在形成机理、膜表面微观结构等方面进行了系统实验研究。结果表明,聚吡咯薄膜大过电位现象在水相条件也存在,同时具有选择性吸附电流特点,产生这一现象与掺杂阴离子性质、种数、浓度及由此而导致的聚合有序性相关。负
关键词 :
吸附电流 ,
导电聚吡咯 ,
薄膜结构 ,
大过电位
Abstract :The large overpotential of the Polypyrrole film is interesting but generally ignored,in this paper,the formation theory of the large overpotential and surface microcosmic structure change of the film are studied systemically.The results indicate that the
Key words :
large overpotential
conductive polypyrrole
adsorptive current
film structure;
出版日期: 2006-08-28
引用本文:
黄赣辉; 邓少平; 詹月华. 导电聚吡咯薄膜的大过电位现象[J]. 南昌大学学报(理科版), 2006, 30(04): 1-.
HUANG Gan-hui~(1,2),DENG Shao-ping~(2*),ZHAN Yue-hua~2(1.The Key Laboratory of Food Science of MOE,Nanchang University,Nanchang 330047,China;2.Sensory Science Laboratory,Zhejiang Gongshang University,Hangzhou 310035,China). . , 2006, 30(04): 1-.
链接本文:
http://qks.ncu.edu.cn/Jwk_xblxb/CN/ 或 http://qks.ncu.edu.cn/Jwk_xblxb/CN/Y2006/V30/I04/1